Can all named stars listed in the hand control be used for alignment?

No, only stars brighter than or equal to magnitude 2.5 can be used for SkyAlign. Even though there are about 250 named stars in the hand control database, only 82 can be used for alignment and related tasks. Here is the list:

Star Mag. Constellation name
Sirius -1.5 Alpha CMa
Canopus -0.7 Alpha Car
Arcturus 0 Alpha Boo
Vega 0 Alpha Lyr
Capella 0.1 Alpha Aur
Rigel 0.1 Beta Ori
Procyon 0.4 Alpha CMi
Achernar 0.5 Alpha Eri
Betelgeuse 0.5 Alpha Ori
Hadar 0.6 Beta Cen
Altair 0.8 Alpha Aql
Aldebaran 0.9 Alpha Tau
Spica 1 Alpha Vir
Antares 1 Alpha Sco
Pollux 1.1 Beta Gem
Fomalhaut 1.2 Alpha Psc
Acrux 1.3 Alpha Cru
Mimosa 1.3 Beta Cru
Alpha Centauri 1.3 Alpha Cen
Deneb 1.3 Alpha Cyg
Regulus 1.4 Alpha Leo
Adhara 1.5 Epsilon CMa
Bellatrix 1.6 Gamma Ori
Gacrux 1.6 Gamma Cru
Shaula 1.6 Lambda Sco
Alnilam 1.7 Epsilon Ori
El Nath 1.7 Beta Tau
Miaplacidus 1.7 Beta Car
Alnair 1.7 Alpha Gru
Mirfak 1.8 Alpha Per
Wezen 1.8 Delta CMa
Regor 1.8 1 Vel
Dubhe 1.8 Alpha UMa
Alioth 1.8 Epsilon UMa
Menkalinan 1.9 Beta Aur
Alhena 1.9 Gamma Gem
Avior 1.9 Epsilon Car
Alkaid 1.9 Eta UMa
Atria 1.9 Alpha TrA
Sargas 1.9 Theta Sco
Kaus Australis 1.9 Epsilon Sgr
Peacock 1.9 Alpha Pav
Diphda 2 Beta Cet
Hamal 2 Alpha Ari
Polaris 2 Alpha UMi
Mirzam 2 Beta CMa
Castor 2 Alpha Gem
Alphard 2 Alpha Hya
Alpheratz 2.1 Alpha And
Mirach 2.1 Beta And
Algol 2.1 Beta Per
Alnitak 2.1 Zeta Ori
Saiph 2.1 Kappa Ori
Denebola 2.1 Beta Leo
Kochab 2.1 Beta UMi
Menkent 2.1 Theta Cen
Rasalhague 2.1 Alpha Oph
Nunki 2.1 Sigma Sgr
Schedar 2.2 Alpha Cas
Mintaka 2.2 Delta Ori
Suhail 2.2 Lambda Vel
Muhlifain 2.2 Gamma Cen
Alphecca 2.2 Alpha CrB
Eltanin 2.2 Gamma Dra
Sadr 2.2 Gamma Cyg
Caph 2.3 Beta Cas
Almach 2.3 Gamma And
Naos 2.3 Zeta Pup
Scutulum 2.3 Iota Car
Mizar 2.3 Zeta UMa
Dschubba 2.3 Delta Sco
Ankaa 2.4 Alpha Phe
Merak 2.4 Beta UMa
Phad 2.4 Gamma UMa
Sabik 2.4 Eta Oph
Alderamin 2.4 Alpha Cep
Enif 2.4 Epsilon Peg
Scheat 2.4 Beta Peg
Tsih 2.5 Gamma Cas
Menkar 2.5 Alpha Cet
Aludra 2.5 Eta CMa
Markab 2.5 Alpha Peg